Mixing tomato ketchup with horseradish causes it to gel over night
A while ago a reader sent me a very interesting question regarding a gelled seafood sauce. It is made by mixing tomato ketchup with horseradish and his question was very simple: Why and how does this sauce gel? He speculated about pectin (which is present in tomatoes), but wondered why ketchup then doesn’t gel on it’s own? And he also noted that horseradish ground with water does not have any gel like properties. So how come they can form a gel when mixed together?
The first thing that came to my mind was a previous blogpost on tomato gels with the pectin that’s there. Pectin in tomatoes is highly methylated (HM), meaning that a lot of sugar would be required for it to gel and that gelling is not promoted by calcium. But if it is mixed with juice from carrots or oranges which contain the enzyme pectin methylesterase (PME), the methyl groups are cleaved off (as shown below) to yield a low methylated (LM) type of pectin which will gel more easily, especially in the presence of calcium ions. Could something similar be the case in the gelled seafood sauce?
Once horseradish is cut, enzymes start to break down sinigrin to release allyl isothiocyanate (mustard oil) which is responsible for the pungent taste and the irritating effect on the eyes and sinuses. In biochemistry, horseradish is best known for an enzyme called horseradish peroxidase. I’m not sure if this is the enzyme that is responsible for the degradation of sinigrin, but adding together the bits and pieces my best guess is that some enzyme in horseradish does more or less the same thing as pectin methylesterase, cleaving of methyl groups to make the pectin more prone to gel. I haven’t been able to find any papers on this though, so if any readers know more about his – please feel free to fill me inn! And can you think of other foods where horseradish advantageously could be used for gelling?
Using an Aeropress as a pressure filter to obtain a horseradish extract
Before writing this blog post I wanted to test the gelling, so I took a pieces of horseradish, peeled it and grated it. The gratings were quite dry so I decided to mixed them with some water and then filter the mixture to obtain a horseradish extract. The Areopress coffee maker turned out to be perfect for this (as shown in the picture above). I then mixed the extract with approximately 6-8 times the amount of ketchup and left it in the fridge to gel. A before-and-after picture of the ketchup mixed with the horseradish extract is shown below. If I would make this again however, I’d probably not bother about filtration – instead I would use a food processor with knives to break up the cells in the horseradish as much as possible to maximize the release of the intracellular enzymes.
Ketchup and horseradish extract immediately after mixing (left) and after a night in the fridge (right)
The suggested recipe I received with the question was as follows (more can be found by googling “seafood sauce” or “cocktail sauce” in combination with ketchup and horseradish):
Gelled seafood sauce
250 mL horseradish
4 L ketchup to
25 mL lemon juice
Grate/grind horseradish with a little water. Mix with ketchup. Adjust with lemonjuice (and possibly salt) to taste. Refridgerate. The gelling doesn’t happen until a day or so later.